Chemistry 205

Syllabus

Course Outline
TopicText ReferenceSuggested Homework
Covalent Bonding and Shapes of Molecules:
Electronic Structure of Atoms, Lewis Model of Bonding, Functional Groups, Bond Angles and Shapes of Molecules, Polar and Nonpolor Molecules, Resonance, Molecular Orbital and Valence Bond Theories of Covalent Bonding
Chapter 1Ch.1 pp.48-55: 31, 37, 46
Alkanes and Cycloalkanes:
Structure, Isomerism, Nomenclature, IUPAC System, Physical Properties, Reactions, Sources and Importance of Alkanes and Cycloalkanes
Chapter 2Ch.2 pp.103-110: 16, 17, 18, 20, 25, 27, 28, 29, 30, 35, 46, 54
Stereochemistry and Chirality:
Stereoisomerism, Chirality, R,S System, Properties, Optical Activity, Separation, Significance
Chapter 3 
Acids and Bases:
Arrhenius Acids and Bases, Brønsted-Lowry Acids and Bases, Acid Dissociation Constants, Equilibrium, Molecular Structure and Acidity
Chapter 4 
Exam One (1-4) September 24th  
Alkenes:
Structure, Nomenclature, Physical Properties, Terpenes
Chapter 5Ch.5 pp.198-203: 13, 14, 15, 20, 24, 30, 31, 34
Reactions of Alkenes:
Overview, Mechanisms, Electrophilic Additions, Hydroboration-Oxidations, Oxidation, Reduction, Chiral Centers
Chapter 6Ch.6 pp.251-263: 14, 16, 17, 18, 23, 27, 31, 32, 36, 47
Alkynes:
Structure, Nomenclature, Physical Properties, Acidity, Preparation, Electrophilic Addition, Hydration, Reduction, Synthesis
Chapter 7Ch.7: pp.286-291: 10, 11, 12, 14, 16, 17, 23, 24
Haloalkanes, Halogenations and Radical Reactions:
Structure, Nomenclature, Physical Properties, Preparation, Mechanism of Halogenation, Allylic Halogenation, Radical Autoxidation, Radical Addition
Chapter 8Ch.8 pp.323-328: 8, 9, 13, 24, 28, 29, 30
Exam Two (5-8) - November 5th  
Nucleophilic Substitutions and β-Eliminations:
Overview, Solvents, Mechanisms, Experimental Evidence, Analysis, Phase-Transfer Catalysis
Chapter 9 
AlcoholsChapter 10 
Ethers, Sulfides, and Epoxides:
Structure, Nomenclature, Physical Properties, Acidity and Basicity, Reactions, Acid-Catalyzed Dehydration, Pinacol Rearrangement, Oxidation, Thiols
Chapter 11 
Exam Three (9-11) - December 3rd  
Benzene and Aromaticity:
Structure, Aromaticity, Nomenclature, Phenols, Reactions
Chapters 21, 22 
Comprehensive Final / Exit Exam - December 12thComprehensive 
 
 
Laboratory Schedule:
ExperimentDate
Check-In / Melting Point and Boiling Point DeterminationSept. 5th & Sept. 12th
CrystallizationSept. 19th & Sept. 26th
Organic Lab TechniquesSept. 26th & Oct. 3rd
Synthesis of AspirinOct. 10th
Separation of the Ingredients of ExcedrinOct. 24th
Isolation of Caffeine from Tea 
Preparation of an Alkene 
Infrared Spectroscopy 
Spectroscopic Identification of an Unknown Compound 
NMR Spectroscopy 
Lab Clean-up and Check-Out 

Laboratory Books are due on December 5th. They will not be accepted late.

Laboratory Assignments will be provided to you as handouts. There is no laboratory textbook.